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Errata for the 1st and 2nd
printings and for the 3rd printing of the book (document in
pdf format).
Errata for the 1st and 2nd printings:
Errata for 1st and 2nd printings (last update: 12/04)
Errata for the 3rd printing:
Errata for the 3rd printing (last
update: 12/04)
It is also available the Solutions Manual
with the solutions to all problems presented in the 3rd. edition of Molecular
Thermodynamics of Fluid Phase Equilibria (get here an errata for this Solutions Manual).
To obtain a copy of the Solutions Manual,
please contact one of the authors (EGA) or Prentice- Hall.
Summary:
The classic guide to mixtures, completely updated with new models,
theories, examples, and data. Efficient separation operations and many other
chemical processes depend upon a thorough understanding of the properties
of gaseous and liquid mixtures.
Molecular Thermodynamics of Fluid-Phase Equilibria , Third Edition is a
systematic, practical guide to interpreting, correlating, and predicting
thermodynamic properties used in mixture-related phase-equilibrium
calculations.
Completely updated, this edition reflects the growing maturity of
techniques grounded in applied statistical thermodynamics and molecular
simulation, while relying on classical thermodynamics, molecular physics,
and physical chemistry wherever these fields offer superior solutions.
Detailed new coverage includes:
Techniques for improving separation processes and making them more
environmentally friendly. Theoretical concepts enabling the description
and interpretation of solution properties. New models, notably the
lattice-fluid and statistical associated-fluid theories. Polymer
solutions, including gas-polymer equilibria, polymer blends, membranes,
and gels. Electrolyte solutions, including semi-empirical models for
solutions containing salts or volatile electrolytes.
Coverage also includes: fundamentals of classical thermodynamics of phase
equilibria; thermodynamic properties from volumetric data; intermolecular
forces; fugacities in gas and liquid mixtures;
solubilities of gases and solids in liquids; high-pressure phase
equilibria; virial coefficients for quantum gases; and much more.
Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a
perfect balance between empirical techniques and theory, and is replete
with useful examples and experimental data. More than ever, it is the
essential resource for engineers, chemists, and other professionals
working with mixtures and related processes.
Table of Contents:
1. The Phase
Equilibrium Problem.
2. Classical Thermodynamics of Phase Equilibria.
3. Thermodynamic Properties from Volumetric Data.
4. Intermolecular Forces, Corresponding States and Osmotic Systems.
5. Fugacities in Gas Mixtures.
6. Fugacities in Liquid Mixtures: Excess
Functions.
7. Fugacities in Liquid Mixtures: Models and
Theories of Solutions.
8. Polymers: Solutions, Blends, Membranes, and Gels.
9. Electrolyte Solutions.
10. Solubilities of Gases in Liquids.
11. Solubilities of Solids in Liquids.
12. High-Pressure Phase Equilibria.
Appendix A. Uniformity of Intensive Potentials as a Criterion of Phase
Equilibrium.
Appendix B. A Brief Introduction to Statistical Thermodynamics.
Appendix C. Virial Coefficients for Quantum Gases.
Appendix D. The Gibbs-Duhem Equation.
Appendix E. Liquid-Liquid Equilibria in Binary and Multicomponent
Systems.
Appendix F. Estimation of Activity Coefficients.
Appendix G. A General Theorem for Mixtures with Associating or Solvating
Molecules.
Appendix H. Brief Introduction to Perturbation Theory of Dense Fluids.
Appendix I. The Ion-Interaction Model of Pitzer for Multielectrolyte
Solutions.
Appendix J. Conversion Factors and Constants.
Index.
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